Artic, if it was a plug problem as you are describing wouldnt likely a CEL be generated?
Firstly, I don't think you have a mechanical problem worth looking into.
Secondly, when I say an under preforming plug I'm not meaning that it is not firing. You can look at each plug and see if there is a difference between them, but that could be a result of a under performing cylinder (which you'd rather not find out about)

. I don't think an under preforming plug will set off a code in a 2000 Montana. How would it know which cylinder it was?
If you find one plug different then you could have a new o -ring fitted on that injector I suppose. When it comes to used vehicles like yours my personal opinion is not to go looking for troubles that aren't effecting the daily operation of the unit. Not to offend, but that 3.4 is a turkey and if it runs smoothly then quite frankly it's not worth fretting over because it will run and the something else on the van will die and not be worth repairing and that will be it.
If it were mine I would not waste the syn oil on it year round. I'd get a case of Esso SAE30. that they use in diesels and just change the oil every 4 months and use SAE30 for 8 of those months because that van is operated under severe usage. So from December 1 to April 1 I would use the Esso 3D.